RUB » Faculty of Chemistry and Biochemistry » NanoEC – Electrochemistry & Nanoscale Materials » Publications 2025 » Substrate Diffusion Electrodes for Electrochemical Hydrogenation: Influence of Material Choice and Process Conditions
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10. November 2025

Substrate Diffusion Electrodes for Electrochemical Hydrogenation: Influence of Material Choice and Process Conditions

Jonas Wolf, Zafer Acar, Fatima Shahrour, Yannick Weidemann, Dr. Sheila Hernandez, Dr. Pouya Hosseini, Dr. Kevinjeorjios Pellumbi, Dr. Julian Tobias Kleinhaus, Leon Wickert, Dr. Sebastian Sanden, Prof. Dr. Kristina Tschulik, Prof. Dr. Ulf-Peter Apfel, Dr. Daniel Siegmund

ChemCatChem, 2025, 21, e00746

This study explores the substrate diffusion electrode (SDE) and its performance under varying process parameters. Key factors such as separation layer material, electrolyte, catalyst properties, and stoichiometry are investigated for their impact on electrochemical hydrogenation efficiency. The results emphasize the importance of local water and substrate concentration in optimizing faradaic efficiency, offering insights for improving SDE-based reactions.